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Electrochemical Measurements in Cement Extract Solutions on Reinforcing Steel, Previously Conditioned in Concrete

机译:预先在混凝土中调质的钢筋在水泥浸出液中的电化学测量

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摘要

The corrosion behavior of reinforcing steel, previously embedded in concrete and maintained in conditions of corrosion and two regimes (conventional and pulse) of cathodic protection (CP), was characterized using electrochemical measurements in cement extract (CE) solutions of pH 12.6. The investigation aimed at determination of the properties of the product layers, previously formed on the steel surface. The study further allowed evaluation of the CP effectiveness in terms of steel surface oxidation/reduction behavior in the alkaline medium of CE. Based on the similar electrochemical behavior of protected specimens, it can be concluded that the pulse CP is as effective as the conventional CP regime. Moreover, the surface film, formed in pulse CP conditions appears to be more homogeneous and resistive, compared to the conventional CP regime.
机译:通过在pH 12.6的水泥提取物(CE)溶液中进行电化学测量,表征了预先埋入混凝土中并在腐蚀和两种阴极保护(CP)制度下保持的钢筋的腐蚀行为。该研究旨在确定先前在钢表面上形成的产品层的性能。该研究进一步允许根据CE碱性介质中钢表面的氧化/还原行为来评估CP有效性。基于受保护样品的相似电化学行为,可以得出结论,脉冲CP与常规CP方案一样有效。而且,与常规的CP方案相比,在脉冲CP条件下形成的表面膜显得更均匀且电阻更大。

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